N-(3,4-Dichlorophenyl)thiourea
نویسندگان
چکیده
In the title compound, C(7)H(6)Cl(2)N(2)S, the benzene ring and the mean plane of the thio-urea fragment [-N-C(=S)-N] make a dihedral angle of 66.77 (3)°. Inter-molecular N-H⋯S and N-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional network.
منابع مشابه
3-Acetyl-1-(2,3-dichlorophenyl)thiourea
In the crystal structure of the title compound, C(9)H(8)Cl(2)N(2)OS, there are two mol-ecules in the asymmetric unit which are connected by a pair of N-H⋯S hydrogen bonds. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation of each molecule.
متن کامل1-(2,6-Dichlorobenzoyl)-3-(3,5-dichlorophenyl)thiourea
The crystal structure of the title compound, C(14)H(8)Cl(4)N(2)OS, is composed of discrete mol-ecules with bond lengths and angles quite typical for thio-urea compounds of this class. The plane containing the central SONNCC atom set subtends a dihedral angle of 31.47 (3)° with the benzene ring. An intra-molecular N-H⋯O hydrogen bond stabilizes the mol-ecular conformation and the mol-ecules form...
متن کامل3-Acetyl-1-(2,6-dichlorophenyl)thiourea
In the title compound, C(9)H(8)Cl(2)N(2)OS, the conformation of one of the N-H bonds is anti to the C=S group and the other is anti to the C=O group. Further, the conformations of the amide C=S and the C=O group are anti to each other. The 2,6-dichloro-phenyl ring and the 3-acetyl-thio-urea side chain are inclined to one another at a dihedral angle of 83.44 (5)°. An intra-molecular N-H⋯O hydrog...
متن کامل1-[2-(3,4-Dichlorophenyl)-5-(3,4,5-trimethoxyphenyl)-2,3-dihydro-1,3,4-oxadiazol-3-yl]ethanone
The title compound, C(19)H(18)Cl(2)N(2)O(5), was synthesized by the reaction of N'-(3,4-dichloro-benzyl-idene)-3,4,5-trimethoxy-benzo-hydrazide and acetic anhydride. The oxadiazole ring makes dihedral angles of 82.82 (7) and 9.92 (7)° with the 3,4-dichloro-benzene and the 3,4,5-trimethoxy-benzene ring planes, respectively. The crystal structure is stabilized by inter-molecular C-H⋯ O and C-H⋯ N...
متن کامل1-Chloro-4-(3,4-dichlorophenyl)-3,4-dihydronaphthalene-2-carbaldehyde
The title compound, C(17)H(11)Cl(3)O, was synthesized via the Vilsmeier-Haack reaction. The dihydro-naphthalene ring system is non-planar, the dihedral angle between the two fused rings being 10.87 (13)°; it forms a dihedral angle of 81.45 (10)° with the dichloro-phenyl ring. The crystal structure features inter-molecular C-H⋯O hydrogen bonds.
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